Synthesis-structure-property relationships in new electrode materials for "beyond-lithium" batteries

Increasing power demands of electronics put ever-more demanding constraints on the energy density and power capabilities of lithium-ion batteries, whilst emerging applications such as large-scale energy storage will have different requirements, with cost and sustainability being at the forefront. These challenges cannot be met by current electrode materials, necessitating the discovery of new materials with improved physical properties. This project will investigate synthetic routes to new materials for beyond-lithium batteries (e.g. Na-ion, Mg-ion, aqeuous) and evaluate their electrochemical performance. Structure-property relationships in new materials will be elucidated using in situ and ex situ x-ray and neutron diffraction, X-ray absorption spectroscopy (XAS) and pair distribution function (PDF) analysis. The information from these studies will aid the design of new electrode materials with optimised electrochemical properties.

The project will involve aspects of materials synthesis, electrochemical characterisation and advanced X-ray powder diffraction characterisation and modelling, and will provide extensive training in a range of state-of-the-art research techniques, which are directly applicable to a career in academia or industry. The student will also receive training in a diverse range of transferable skills, ensuring competitiveness in any employment sector.

Funding Notes

Candidates should have or expect to receive a first or upper second (2.1) honours degree (or equivalent) in chemistry, physics, materials science or other related discipline. Familiarity with solid-state chemistry, electrochemistry or crystallographic methods would be an advantage. Applications should be made through the University of Birmingham's online application system. Please contact Dr Phoebe Allan in advance of applying, providing a CV and cover letter summarising your research interests and previous experience. Further information can be obtained by emailing Dr Phoebe Allan (p.allan@bham.ac.uk). For additional information about applications and funding streams, please visit: www.birmingham.ac.uk/schools/chemistry/phd/phd.aspx